Scientific program 01

Atmospheric oxidation

Using distinctive isotope signatures and chemical measurements to investigate ozone-mediated oxidation, reactive nitrogen, particulate matter, and pollution-related processes.

Scientific rationale

Ozone carries an unusual oxygen-isotope composition. When ozone participates in oxygen-transfer chemistry, part of that signature can be inherited by reaction products, providing a tracer of oxidation pathways.

The laboratory applies this concept to particulate nitrate and related pollution chemistry. Current directions also connect particulate composition and chemical reactivity with environmental epidemiology, with the goal of moving beyond particle mass alone toward mechanistic exposure indicators.

Questions guiding the program

  1. Which oxidation pathways dominate particulate nitrate formation under East Asian atmospheric conditions?
  2. How can ozone-derived isotope signals distinguish among competing chemical pathways?
  3. Which particulate components control oxidative capacity and potential biological relevance?
  4. How can atmospheric chemistry and epidemiological evidence be integrated without overstating causal inference?

Starting points in the literature

Browse publications by theme →
SelectedACS Omega · 2025

Novel Triple-Oxygen Isotope Study Indicates Unprecedented Ozone–Particulate Interaction Pathways in Atmospheric Pollution Chemistry

A recent PI-led application of triple oxygen isotopes to ozone–particulate interactions.

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SelectedAtmosphere · 2021

Atmospheric effects on the isotopic composition of ozone

A PI-led study of processes influencing ozone isotope composition.

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SelectedAtmospheric Environment · 2017

Isotopic ratios of nitrate in aerosol samples from Mt. Lulin, a high-altitude station in Central Taiwan

A selected collaborative application of nitrate isotopes in regional atmospheric chemistry.

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SelectedJGR: Atmospheres · 2014

Ammonium deficiency caused by heterogeneous reactions during a super Asian dust episode

A selected study connecting aerosol composition and heterogeneous processing.

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Data and methods will be linked as they are prepared for public release.